Rob and Kristen kicked off their year of 2011 PDA at the MTV Movie Awards and Dr. Glass was right when she told us we'd see more of it! "The fact that Rob and Kristen kept looking directly into each other's eyes throughout the show indicates how completely in sync they are with each other and that they are a total unit."

Browse our gallery of Hollywood's most surprising couples & vote for the one that shocked you most!

Sometimes two celebrities are so perfect for each other, you could never picture either one of them with anyone else -- but what fun is that? HollywoodLife.com is taking a look at some of our favorite recent "WTF" couples, from Doug Hutchison and his teen brideCourtney Stodden to Jennifer Lopez and surprise rebound -- her 24-year-old backup dancer, Casper Smart!

Blake Lively shocked the world when she secretly started hooking up with Leonardo DiCaprio and suddenly became his number one girl.

Vanessa Hudgens broke her fans' hearts when she broke things off with Zac Efron to be with Josh Hutcherson. However, what really surprised everyone was her relationship with the adorable Austin Butler, especially because he hung out in her friend circle when she was with Zac!

After George Clooney's relationship with Elisabetta Canalis went south, he quickly rebounded with another former Dancing with the Stars competitor and ex-wrestler Stacy Keibler. Did YOU see that coming? Neither did we!

There was no relationship this year perhaps more unexpected than the one between Sean Penn, 51, and Scarlett Johansson, 27. Not surprisingly, the love story between the two faded out rather quickly.

First it was Bradley Cooper, and then Jennifer Lopez fell for her 24-year-old backup dancer, Casper Smart! While we're impressed by Casper's resume (he's danced with EVERYONE), J. Lo's ex-husband, Marc Anthony, is less than pleased with Casper being around their toddler twins.

Okay, so Kylie Jenner and Cody Simpson aren't a totally shocking celebrity couple. They are both young, darling and blossoming A-listers. However, we thought it was funny how quickly sparks flew. After they met at the Breaking Dawn premiere in LA, they started dating right away.

Blake Lively sure has had a busy year! After dating Leonardo DiCaprio, the 24-year-old Gossip Girl actress quickly fell for Ryan Reynolds. She even would take the train out to Boston from NYC just for the night to see Ryan when he was shooting.

Nikki Reed and Paul McDonald were definitely one of the most random couples of 2011. The Twilight actress is a huge American Idol fan and met Paul when he was a contestant last season. They quickly fell in love and were married last fall.

The Vampire Diaries actor Taylor Kinney, 30, metLady Gaga, 25, on the set of her "Yoü And I" video -- but their surprise chemistry kept up long after the cameras stopped rolling.

51-year-old Lost actor Doug Hutchison revealed his marriage to then-16-year-old Courtney Stodden in July 2011. In a disturbing interview, Doug defended theirMay-December romance by saying, "Fifty-one plus sixteen equals love."

Ashton's affair and Kim's 72-day marriage were two of the biggest betrayals of the year.

Ashton Kutcher cheated on Demi Moore with Sara Leal and got caught. Kim Kardashian promised her fans a fairy tale wedding to Kris Humphries and she delivered -- but then she filed for divorce 72 days later. Which other stars betrayed their loved ones or fans in 2011?

Yes, it's not as bad as cheating on your wife, or fathering a love child with your maid, but when Robert Pattinson cut his hair for his role in Cosmopolis, all of us R-Patz lovers were devastated by his shocking new 'do. Luckily, his luscious locks have since grown back.

Poor Miley Cyrus. Someone filmed her at her 19th birthday party where she joked about smoking a ton of pot and then leaked it to the press. Whether or not she smokes, Miley does always say she is not a role model so we think she should be left alone.

Kim Kardashian filed for divorce from Kris Humphries 72 days after their wedding, upsetting not only Kris -- who claimed to be blindsided -- but her fans who had watched their relationship unfold on TV.

Mariah Yeater filed a lawsuit against Justin Bieber claiming that the singer was the father of her infant son. She quickly dropped the suit after texts revealed that she told other people her ex-boyfriend was the baby's daddy.

After an alleged drug-bender and a lot of tiger's blood, Charlie Sheen publicly attacked his Two And A Half Men boss Chuck Lorre, which lead to Charlie's firing from the hit series. He later apologized, but the damage had been done.

In an interview with Parade, Brad Pitt bashed his ex-wife Jennifer Aniston, by calling their marriage "dull" and "pathetic." He quickly backtracked on his remarks, but it was too little, too late.

Ashton Kutcher's affair with Sara Leal forced Demi Moore to announce she was leaving her husband of six years.

In 2011, it was revealed that Arnold Schwarzenegger fathered a teenage love-child with his housekeeper Mildred Baena. Maria Shriver filed for divorce from Arnold shortly thereafter.

Former congressman Anthony Weiner "accidentally" tweeted a pic of his well ... weiner, causing a firestorm in the media, ending in his resignation. His wife Huma Abedin stuck by her hubby's side, though, and recently gave birth to the couple's first child.

Rob and Kristen kicked off their year of 2011 PDA at the MTV Movie Awards and Dr. Glass was right when she told us we'd see more of it! "The fact that Rob and Kristen kept looking directly into each other's eyes throughout the show indicates how completely in sync they are with each other and that they are a total unit."

Browse our gallery of Hollywood's most surprising couples & vote for the one that shocked you most!

Sometimes two celebrities are so perfect for each other, you could never picture either one of them with anyone else -- but what fun is that? HollywoodLife.com is taking a look at some of our favorite recent "WTF" couples, from Doug Hutchison and his teen brideCourtney Stodden to Jennifer Lopez and surprise rebound -- her 24-year-old backup dancer, Casper Smart!

Blake Lively shocked the world when she secretly started hooking up with Leonardo DiCaprio and suddenly became his number one girl.

Vanessa Hudgens broke her fans' hearts when she broke things off with Zac Efron to be with Josh Hutcherson. However, what really surprised everyone was her relationship with the adorable Austin Butler, especially because he hung out in her friend circle when she was with Zac!

After George Clooney's relationship with Elisabetta Canalis went south, he quickly rebounded with another former Dancing with the Stars competitor and ex-wrestler Stacy Keibler. Did YOU see that coming? Neither did we!

There was no relationship this year perhaps more unexpected than the one between Sean Penn, 51, and Scarlett Johansson, 27. Not surprisingly, the love story between the two faded out rather quickly.

First it was Bradley Cooper, and then Jennifer Lopez fell for her 24-year-old backup dancer, Casper Smart! While we're impressed by Casper's resume (he's danced with EVERYONE), J. Lo's ex-husband, Marc Anthony, is less than pleased with Casper being around their toddler twins.

Okay, so Kylie Jenner and Cody Simpson aren't a totally shocking celebrity couple. They are both young, darling and blossoming A-listers. However, we thought it was funny how quickly sparks flew. After they met at the Breaking Dawn premiere in LA, they started dating right away.

Blake Lively sure has had a busy year! After dating Leonardo DiCaprio, the 24-year-old Gossip Girl actress quickly fell for Ryan Reynolds. She even would take the train out to Boston from NYC just for the night to see Ryan when he was shooting.

Nikki Reed and Paul McDonald were definitely one of the most random couples of 2011. The Twilight actress is a huge American Idol fan and met Paul when he was a contestant last season. They quickly fell in love and were married last fall.

The Vampire Diaries actor Taylor Kinney, 30, metLady Gaga, 25, on the set of her "Yoü And I" video -- but their surprise chemistry kept up long after the cameras stopped rolling.

51-year-old Lost actor Doug Hutchison revealed his marriage to then-16-year-old Courtney Stodden in July 2011. In a disturbing interview, Doug defended theirMay-December romance by saying, "Fifty-one plus sixteen equals love."

Ashton's affair and Kim's 72-day marriage were two of the biggest betrayals of the year.

Ashton Kutcher cheated on Demi Moore with Sara Leal and got caught. Kim Kardashian promised her fans a fairy tale wedding to Kris Humphries and she delivered -- but then she filed for divorce 72 days later. Which other stars betrayed their loved ones or fans in 2011?

Yes, it's not as bad as cheating on your wife, or fathering a love child with your maid, but when Robert Pattinson cut his hair for his role in Cosmopolis, all of us R-Patz lovers were devastated by his shocking new 'do. Luckily, his luscious locks have since grown back.

Poor Miley Cyrus. Someone filmed her at her 19th birthday party where she joked about smoking a ton of pot and then leaked it to the press. Whether or not she smokes, Miley does always say she is not a role model so we think she should be left alone.

Kim Kardashian filed for divorce from Kris Humphries 72 days after their wedding, upsetting not only Kris -- who claimed to be blindsided -- but her fans who had watched their relationship unfold on TV.

Mariah Yeater filed a lawsuit against Justin Bieber claiming that the singer was the father of her infant son. She quickly dropped the suit after texts revealed that she told other people her ex-boyfriend was the baby's daddy.

After an alleged drug-bender and a lot of tiger's blood, Charlie Sheen publicly attacked his Two And A Half Men boss Chuck Lorre, which lead to Charlie's firing from the hit series. He later apologized, but the damage had been done.

In an interview with Parade, Brad Pitt bashed his ex-wife Jennifer Aniston, by calling their marriage "dull" and "pathetic." He quickly backtracked on his remarks, but it was too little, too late.

Ashton Kutcher's affair with Sara Leal forced Demi Moore to announce she was leaving her husband of six years.

In 2011, it was revealed that Arnold Schwarzenegger fathered a teenage love-child with his housekeeper Mildred Baena. Maria Shriver filed for divorce from Arnold shortly thereafter.

Former congressman Anthony Weiner "accidentally" tweeted a pic of his well ... weiner, causing a firestorm in the media, ending in his resignation. His wife Huma Abedin stuck by her hubby's side, though, and recently gave birth to the couple's first child.