Zachary Levi arrives at the 2012 People’s Choice Awards at Nokia Theatre L.A. Live on January 11, 2012 in Los Angeles, California. (Getty Images)

LOS ANGELES, CA – JANUARY 11: Actresses Portia de Rossi and Ellen DeGeneres pose backstage during the 2012 People’s Choice Awards at Nokia Theatre L.A. Live on January 11, 2012 in Los Angeles, California. (Photo by Christopher Polk/Getty Images for PCA)

LOS ANGELES, CA – JANUARY 11: Alyson Hannigan and Alexis Denisof attend People’s Choice Awards 2012 at Nokia Theatre LA Live on January 11, 2012 in Los Angeles, California. (Photo by Jeffrey Mayer/WireImage)

Demi Lovato perfoms during the People’s Choice Awards on Wednesday, Jan. 11, 2012 in Los Angeles. (AP Photo/Chris Pizzello)

LOS ANGELES, CA – JANUARY 11: David Boreanaz and Jaime Bergman attend People’s Choice Awards 2012 at Nokia Theatre LA Live on January 11, 2012 in Los Angeles, California. (Photo by Jeffrey Mayer/WireImage)

LOS ANGELES, CA – JANUARY 11: TV Personalities Gene Simmons and Shannon Tweed arrive at the 2012 People’s Choice Awards at Nokia Theatre L.A. Live on January 11, 2012 in Los Angeles, California. (Photo by Frazer Harrison/Getty Images for PCA)

Rachel Crow arrives at the 2012 People’s Choice Awards at Nokia Theatre L.A. Live on January 11, 2012 in Los Angeles, California. (Getty Images)

Ginnifer Goodwin looked bright in a hot pink Roksanda Ilincic Spring 2012 frock and Jimmy Choo booties.

Emma Stone’s ensemble was definitely a bit dressed down compared to the other a-lister’s, but the star looked just as chic in an emerald Gucci blazer.

Jennifer Lawrence knows how to keep things interesting on the red carpet, and that’s exactly what she did in a blue Viktor & Rolf dress, Sergio Rossi shoes, and Jack Vartanian jewelry.

Ashley Benson worked a black and white alice + olivia frock, looking sweet and chic on the red carpet!

Lucy Hale was red-carpet-ready in her Cengiz Abazoglu dress.

The hostess of the evening, Kaley Cuoco, rocked the red carpet and followed the pastel trend in a pale pink Badgley Mischka gown, complete with embroidered detail. She accessorized with an Anna Sheffield Bridal ring.

Vanessa Hudgens sparkled in a Jenny Packham gown.

Nina Dobrev looked sexy in a green Elie Saab frock with sheer sleeves.

Kelly Osbourne turned up in a colorblock Honor frock.

Cheryl Burke showed off a shimmering Chagoury Couture dress, complete with sexy slit, on the red carpet. She accessorized with a Simon G cuff and ring.

Chloe Moretz looked adorable and age appropriate in Proenza Schouler.

Lea Michele got glam in an intricate white Marchesa dress.

Check out the stunning stars on the People’s Choice Awards red carpet and VOTE for who you think was best dressed!

Some of our favorite a-listers were out in full force, dressing their best on the red carpet for the 2012 People’s Choice Awards. We saw pretty pastels, plunging necklines, leather and sexy slits on everyone from Miley Cyrus to Nina Dobrev and Ashley Greene! Check out who else made our best dressed list & VOTE for which frock was your fave.

Katrina Mitzeliotis

Demi Lovato looked sexy and elegant in a gorgeous strapless Marchesa gown.

Miley Cyrus looked sexy and chic in a David Koma dress. She accessorized with Neil Lane studs, Jimmy Choo heels, and a Marchesa bag.

Ashley Greene looked edgy in a leather and lace DKNY dress. She complimented her frock with an exquisite Black Diamond Floral Cuff and Chandelier Earrings by Jacob & Co.

Kristen Bell looked radiant in a lace top and leather skirt, both by Valentino. She accessorized with Anita Ko rose gold spiked stud earrings.

Jennifer Morrison opted for a chic Oscar de la Renta frock.

Julianne Hough looked sexy in a sparkling, backless long-sleeved dress.She accessorized with a Palladium ring and earrings.

Check out celebs with silkily waves and side swept strands mixed with pink lipstick and long lashes. See all the looks and VOTE on you favorite!

The 2012 People’s Choice Awards is definitely a time for fun and funky hair and makeup choices to mingle with classic glam looks. Miley Cyrus was the picture of perfection with her sleek blonde strands draped over her shoulder and goddess-like makeup. Demi Lovato tried a dramatic updo and peachy makeup that complimented her dress perfectly. See the top beauty looks of the evening and vote below on which star you think should win the title of best beauty!